Revisiting the long-range Perlin effect in a conformationally constrained oxocane
Kahlil S. Salome, Cláudio F. Tormena
ARTIGO
Inglês
Agradecimentos: We acknowledge FAPESP for financial support (2015/08541-6) and CAPES for scholarships to K.S.S. We are grateful for fellowships from CNPq to C.F.T
Unusual 1JCH values for an oxocane derivative were recently reported, highlighting the unexpected long-range Perlin effect for the 1JCH. According to our theoretical and experimental results listed in this paper, the previous published data cannot be supported. Moreover, when comparing the...
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Unusual 1JCH values for an oxocane derivative were recently reported, highlighting the unexpected long-range Perlin effect for the 1JCH. According to our theoretical and experimental results listed in this paper, the previous published data cannot be supported. Moreover, when comparing the previously studied oxocane derivative with analogous molecules, we realized that the difference between J-couplings actually comes from the increase in the 1JC–Hax instead of decreasing of 1JC–Heq, as suggested
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FUNDAÇÃO DE AMPARO À PESQUISA DO ESTADO DE SÃO PAULO - FAPESP
2015/08541-6
COORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES
Fechado
DOI: https://doi.org/10.1021/acs.joc.8b00935
Texto completo: https://pubs.acs.org/doi/10.1021/acs.joc.8b00935
Revisiting the long-range Perlin effect in a conformationally constrained oxocane
Kahlil S. Salome, Cláudio F. Tormena
Revisiting the long-range Perlin effect in a conformationally constrained oxocane
Kahlil S. Salome, Cláudio F. Tormena
Fontes
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Journal of organic chemistry Vol. 83, no. 17 (Aug., 2018), p. 10501-10504 |