Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/99459
Type: Artigo de periódico
Title: Synthesis Of (chloromercurio)pentakis(t-butyl Isocyanide)iron Complexes
Author: Morigaki M.K.
Dias G.H.M.
Abstract: The isocyanide-complex [Fe(t-BuNC)5] reacts with mercury(II) chloride in petroleum ether, to give the novel oxidative addition products [Fe(t-BuNC)5(HgCl)]+·[HgCl3]- (1) or [Fe(t-BuNC)5(HgCl)]2+ [HgCl4]2- (2). Complex (2) is also obtained upon treating solutions of (1) with Na+[BH4]-, Na, or by addition of NaCl. Complex (1) reacts with [Fe(CO)5] to yield either (2) or [Fe(t-BuNC)5(HgCl)]+Cl- (3), depending upon the molar ratio of reactants. Complex (1) reacts with NH4+ [PF6]-, in the presence of t-butyl isocyanide, to give [Fe(t-BuNC)5(HgCl)]+[PF6]- (4). These products have been characterized by elemental analysis, i.r. and n.m.r. spectra, and their ionic formulations established from conductance and molecular weight measurements on solutions. © 1992 Chapman & Hall.
Editor: Springer Netherlands
Rights: fechado
Identifier DOI: 10.1007/BF02910799
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-0041611066&partnerID=40&md5=a99c937c0dc50e54a31f070c7f192ac4
Date Issue: 1992
Appears in Collections:Unicamp - Artigos e Outros Documentos

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