Please use this identifier to cite or link to this item:
Type: Artigo de periódico
Title: Synthesis Of (chloromercurio)pentakis(t-butyl Isocyanide)iron Complexes
Author: Morigaki M.K.
Dias G.H.M.
Abstract: The isocyanide-complex [Fe(t-BuNC)5] reacts with mercury(II) chloride in petroleum ether, to give the novel oxidative addition products [Fe(t-BuNC)5(HgCl)]+·[HgCl3]- (1) or [Fe(t-BuNC)5(HgCl)]2+ [HgCl4]2- (2). Complex (2) is also obtained upon treating solutions of (1) with Na+[BH4]-, Na, or by addition of NaCl. Complex (1) reacts with [Fe(CO)5] to yield either (2) or [Fe(t-BuNC)5(HgCl)]+Cl- (3), depending upon the molar ratio of reactants. Complex (1) reacts with NH4+ [PF6]-, in the presence of t-butyl isocyanide, to give [Fe(t-BuNC)5(HgCl)]+[PF6]- (4). These products have been characterized by elemental analysis, i.r. and n.m.r. spectra, and their ionic formulations established from conductance and molecular weight measurements on solutions. © 1992 Chapman & Hall.
Editor: Springer Netherlands
Citation: Transition Metal Chemistry. Springer Netherlands, v. 17, n. 2, p. 115 - 118, 1992.
Rights: fechado
Identifier DOI: 10.1007/BF02910799
Date Issue: 1992
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File SizeFormat 
2-s2.0-0041611066.pdf415.63 kBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.