Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/99357
Type: Artigo de periódico
Title: Trimethylsilyl Trifluoromethanesulfonate (tmsotf) Catalyzed Amidoalkylation Of Silylenolethers. Stereocontrolled Syntheses Of (+/-)-sedamine And (+/-)-norsedamine
Author: Pilli R.A.
Dias L.C.
Abstract: Trimethylsilyl trifluoromethanesulfonate (TMSOTf) catalyzed addition of 1-trimethylsilyloxy-1-phenylethene to N-ethoxycarbonyl- and N-tert-butoxycarbonyl-2-ethoxypiperidines (3a and 3b, respectively) afforded the corresponding ketocarbamates 4a and 4b, in excellent yields. Stereoselective conversion to (±)-norsedamine (7) and (±)-sedamine (8) is described.
Editor: 
Rights: fechado
Identifier DOI: 
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-0026040101&partnerID=40&md5=5ee041327d717a6688a51872fc3c44a5
Date Issue: 1991
Appears in Collections:Unicamp - Artigos e Outros Documentos

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