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Type: Artigo de periódico
Title: Intrazeolite Metal Carbonyl Kinetics: 12co Substitution In Mo(12co)6-na56y By Pme3 And 13co
Author: Ozin G.A.
Ozkar S.
Pastore H.O.
Poe A.J.
Vichi E.J.S.
Abstract: The first kinetic study is reported for archetypical substitution reactions of PMe3 and 13CO with the well defined intrazeolite system, Mo(12CO)6-Na56Y, for which excellent isosbestic points and first order behaviour are obtained, the activation parameters indicate a highly ordered 'supramolecular' transition state consisting of activated Mo(12CO)6 and PMe3 or 13CO all anchored to the Na+ ions in the α-cage of the host lattice.
Rights: aberto
Identifier DOI: 10.1039/C39910000141
Date Issue: 1991
Appears in Collections:Unicamp - Artigos e Outros Documentos

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