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Type: Artigo de periódico
Title: Selective Cyclohexane Oxidation Catalyzed By The Gif System
Author: Schuchardt U.
Mano V.
Abstract: The turnover number and selectivity of the cyclohexane oxidation by the Gif system were studied as functions of the quantities of cyclohexane and catalyst and of the reaction temperature and time. It was found that the cyclohexanone-producing catalytic species is only formed after the reaction has started and that the turnover number decreases after the first 60 min. Under an atmosphere of pure oxygen turnover numbers as high as 100 h -1 were observed, but the Gif system loses its selectivity and reacts with cyclohexanone to produce further compounds. © 1990 Academic Press Inc.
Rights: fechado
Identifier DOI: 10.1016/S0167-2991(08)60148-2
Date Issue: 1990
Appears in Collections:Unicamp - Artigos e Outros Documentos

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