Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/98526
Type: Artigo de periódico
Title: On-line Oxidation Of Cr(lll) To Cr(vi) For Use With The Flow Injection Analysis Technique
Author: De Andrade J.C.
Rocha J.C.
Baccan N.
Abstract: An on-line procedure for the oxidation of Cr(III) to Cr(VI) was developed. The extent of oxidation was followed using the 1,5-diphenylcarbazide (DPC) spectrophotometric method accommodated in a flow injection analysis (FIA) system. Cerium(IV) sulphate and potassium peroxydisulphate were tested as oxidising agents. Despite the high oxidation power of the peroxydisulphate ion in acidic solution, the use of Ce(IV) is more convenient under dynamic conditions. The best experimental conditions were obtained at 45°C using a 0.025% m/\/Ce(IV) solution in 0.07 M H2SO4 with the Cr(III) solutions containing up to 3.0 × 10-2 M H 2S04.
Editor: 
Rights: aberto
Identifier DOI: 
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-0000640969&partnerID=40&md5=bfddfb2759768bd746b6258b3164365a
Date Issue: 1984
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File SizeFormat 
2-s2.0-0000640969.pdf436.98 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.