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Type: Artigo de periódico
Title: Some Features Of The Interaction Of Silica Gel With Organic Bases
Author: Airoldi C.
Santos Jr. L.S.
Abstract: The acid groups attached to a silica gel surface were calorimetrically and chromatographically titrated by N,N-dimethylformamide; N,N-dimethylacetamide; pyridine; methanol; acetone, and acetonitrile in 1,2-dichloroethane. The chromatographic titration furnished the number of moles of solute which reacted with the silanol groups. From the net isotherm fitted to a modified Langmuir equation, the variation of enthalpy and the equilibrium distribution constant of the hydrogen bonding were calculated. The results correlated with the donor number of the bases. The following order of the interaction in forming hydrogen bonding was established: pyridine > N,N-dimethylacetamide > N,N-dimethylformamide > acetone > acetonitrile. © 1986.
Rights: fechado
Identifier DOI: 10.1016/0040-6031(86)85189-9
Date Issue: 1986
Appears in Collections:Unicamp - Artigos e Outros Documentos

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