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Type: Artigo de periódico
Title: X-ray Structure Of (n-heterocyclic)(η4-diene)-dicarbonyliron(0) Compounds
Author: De Paoli M.-A.
Lechat J.R.
Inumaru A.T.
Abstract: (N-Heterocyclic)(η4-diene)dicarbonyliron(0) compounds, where the N-heterocycles are quinoline and pyrazine and the diene is the diethyl ester of the hexa-2,4-dien-1,6-dioic acid (diethyl muconate) were studied by X-ray diffraction. The measurements demonstrated that the N-heterocycle occupies different positions of a tetragonal pyramid in these compounds. Quinoline occupies a basal position and pyrazine an apical position. This is discussed in terms of the π-bonding ability of the ligands. © 1987.
Rights: fechado
Identifier DOI: 10.1016/0022-328X(87)85082-9
Date Issue: 1987
Appears in Collections:Unicamp - Artigos e Outros Documentos

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