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Type: Artigo de periódico
Title: Preferred Conformations Of Methylthio-acetone And -acetophenone, Methylsulphonyl-acetone And -acetophenone, From Molecular-mechanics And Dipole-moment Techniques
Author: Lumbroso H.
Bertin D.M.
Olivato P.R.
Bonfada E.
Mondino M.G.
Hase Y.
Abstract: Preferred conformations for the title compounds are determined from calculated molecular-mechanics energies in the gaseous phase and analysis of the dipole moments measured in solvents of low dielectric permittivity, In all cases, the gauche conformer having the MeS bond situated far away from the Me(C) (or Ph(C)) group, and nearly bisecting one of the C(O)CH valleys, is predominant. © 1989.
Rights: fechado
Identifier DOI: 10.1016/0022-2860(89)85071-9
Date Issue: 1989
Appears in Collections:Unicamp - Artigos e Outros Documentos

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