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Type: Artigo de periódico
Title: Radiationless Processes Of 5,6-diazaphenanthrene In N-hexane And Hexafluoroisopropanol Studied Through The Triplet And Singlet Excited Luminescences
Author: Caetano C.A.
De Paoli M.A.
Pessine F.B.T.
Sanjurjo J.A.
Abstract: In this work we report a luminescence study of 5,6-diazaphenanthrene dissolved in n-hexane and hexafluoroisopropanol with the excitation energies focused in the singlet and triplet manifolds of this molecule. Fluorescence spectra indicate that the lowest excited singlet state is changed from 1(nπ*) in n-hexane to 1(ππ*) in hexafluoroisopropanol at room temperature and low temperatures. The phosphorescence obtained on direct laser excitation of the triplet state is assigned as the 3A1(ππ*) → S0) process for both solutions. The temperature dependence of the luminescence and the relative yields of the T1 → S0 emissions allow us to conclude that the non-phosphorescence of 5,6-diazaphenanthrene in hydrocarbon solvents is determined by the low population of the triplet state. © 1988.
Rights: fechado
Identifier DOI: 10.1016/1010-6030(88)80073-X
Date Issue: 1988
Appears in Collections:Unicamp - Artigos e Outros Documentos

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