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|Type:||Artigo de periódico|
|Title:||Metal Carbonyls With Zinciron Bond: Synthesis And Vibrational Spectra|
|Abstract:||The compounds of the type LZnFe(CO)4 (L = dien, trien, tn, s-diMeen, Meen) not yet reported and (NH3)3ZnFe(CO)4, already known, were prepared and studied by IR and Raman spectroscopy. The data obtained suggest that LZnFe(CO)4, for L = (NH3)3, dien and trien are monomers with a bipyramidal trigonal configuration around the iron atom, while for L = tn, s-diMeen and Meen the complexes are probably polymers having a center of symmetry with iron atoms octahedrally co-ordinated. © 1979.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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