Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/96326
Type: Artigo de periódico
Title: Mössbauer Spectroscopy Of (benzylideneacetone)fe(co)2l Complexes With L = Co, Phosphites And Phosphines. An Analysis Of Ligand Effects
Author: Vichi E.J.S.
Stein E.
Saitovitch E.B.
Abstract: The (benzylideneacetone)Fe(CO)2L complexes, with L = CO, PPh3, PMePh2, PMe2Ph, PEt3, PCy3, P(OPh)3, P(OMe)3, P(OEt)3 and P(OiPr)3 have been studied by Mössbauer spectroscopy. The spectra are compatible with a distorted octahedral geometry with the iron atom at the center. The isomer shifts δ and quadrupole splittings ΔEq are correlated with the Giering electronic parameter χd of the phosphines and phosphites and with the 13C NMR complex shifts ΔC4 of coordinated benzylideneacetone. The results are discussed in terms of the stereoelectronic effects of the ligand L. Correlation between isomer shifts and quadrupole splittings indicates that dπ-Lπ{black star} back bonding is predominant in the complexes with L = CO and phosphites and negligible in the complexes with L = phosphines. © 1994.
Editor: 
Rights: fechado
Identifier DOI: 10.1016/0022-328X(94)88121-9
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-1842490417&partnerID=40&md5=1fdc4ca0542a97584c99185b45de1ce0
Date Issue: 1994
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File Description SizeFormat 
2-s2.0-1842490417.pdf592.05 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.