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Type: Artigo de periódico
Title: Preparation And Mössbauer Study Of Iron-mercury Halide Complexes Containing Isocyanide And Carbonyl Ligands
Author: Morigaki M.K.
Machado L.C.
Larica C.
Dias G.H.M.
Abstract: Complexes [Fe(t-BuNC)n(CO)5-n](n = 1 or 2) react with equimolar amounts of mercury(II) halides in acetone to form neutral iron-mercury adducts [Fe(t-BuNC) (CO)4-(HgX2)] and [Fe(t-BuNC)2(CO)3(HgX2)] (X = Cl or I), while [Fe(t-BuNC)5] reacts with solid mercury halides in petroleum ether to give the salts [Fe(t-BuNC)5(HgX)]-HgX3 (X = Br or I). Product assessment was based upon analytical and spectroscopic data, the Mössbauer effect and on molar conductivity studies. © 1994 Chapman & Hall.
Editor: Kluwer Academic Publishers
Rights: fechado
Identifier DOI: 10.1007/BF00980411
Date Issue: 1994
Appears in Collections:Unicamp - Artigos e Outros Documentos

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