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Type: Artigo de periódico
Title: Nucleophilic Interception Of The γ,δ-acetylenic α,β-olefinic Aldehyde Intermediate Formed From Furil Monotosylhydrazone
Author: Sparrapan R.
Kascheres C.
Gambardella M.T.P.
Abstract: The reaction of furil monotosylhydrazone (1) with nucleophiles under basic conditions led to the formation of 5-(2-furoylmethylene)-2-pyrrolidinones 3 when amines and hydrazine hydrate were used. Treatment with methylhydrazine led to production of 1-methyl-6-(2-furoylmethylene)-pyridazine (4) while treatment with phenylhydrazine and 4-nitrophenylhydrazine produced 1-(2-furoyl)-6-anilino-6-azafulvene (5a) and 1-(2-furoyl)-6-(4-nitroanilino)-6-azafulvene (5b), respectively. All products suggest interception of the γ,δ-acetylenic α,β-olefinic aldehyde intermediate 2 formed via the unstable 1,2-difuryldiazoethanone. © 1995 American Chemical Society.
Rights: fechado
Identifier DOI: 
Date Issue: 1995
Appears in Collections:Unicamp - Artigos e Outros Documentos

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