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Type: Artigo de periódico
Title: Site And Stereoselectivity Of The Cyclopropanation Of Unsymmetrically Substituted 1,3-dienes By The Simmons-smith Reaction
Author: Guerreiro M.C.
Schuchardt U.
Abstract: In the Simmons-Smith reaction, 1,3-dienes are preferentially cyclopropanated at the more electron-rich double bond to afford the trans-vinylcyclopropane; an allylic hydroxyl group increases the reactivity and directs the cyclopropanation to the adjacent double bond.
Rights: fechado
Identifier DOI: 
Date Issue: 1996
Appears in Collections:Unicamp - Artigos e Outros Documentos

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