Please use this identifier to cite or link to this item:
Type: Artigo de evento
Title: Microbial Reduction Of Cyclohexanones
Author: De Conti R.M.
Porto A.L.M.
Augusto J.
Rodrigues R.
Moran P.J.S.
Manfio G.P.
Marsaioli A.J.
Abstract: A Brazilian strain of the bacteria Serratia rubidaea CCT 5742 quantitatively reduced 4-tert-butylcyclohexanone and 4-methylcyclohexanone to the less thermodynamically stable diastereoisomeric alcohols cis-4-tert-butylcyclohexanol and cis-4-methylcyclohexanol with a diastereoisomeric excesses (de) of 96% and 44%, respectively. 2-Methylcyclohexanone was also totally reduced to the corresponding alcohols affording the trans-(+)-(1S, 2S)-2-methylcyclohexanol with 78% of de and an enantiomeric excess (ee) of 80%. The cis-(+)-(1S, 2R)-2-methylcyclohexanol was obtained in 98% ee. Copyright © 2001 Elsevier Science B.V.
Rights: fechado
Identifier DOI: 10.1016/S1381-1177(00)00087-4
Date Issue: 2001
Appears in Collections:Unicamp - Artigos e Outros Documentos

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