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Type: Artigo de periódico
Title: Experimental And Theoretical Study On The Reactivity Of The R-cn/h2o2 System In The Epoxidation Of Unfunctionalized Olefins
Author: Von Holleben M.L.A.
Livotto P.R.
Schuch C.M.
Abstract: A study on the reactivity of peroxycarboximidic acids in situ generated from acetonitrile, trichloroacetonitrile, benzonitrile, m-chlorobenzonitrile, 3-cyanopyridine, 1-naphthonitrile and 9-anthracenenitrile was performed by semiempirical AM1 method and experimentally in the epoxidation of cyclohexene and R-(+)-limonene. Experimental results showed that the reactivity of Cl3CCN/H2O2 was quite similar to MCPBA in the epoxidation of unfunctionalized olefins when a biphasic mixture CH2Cl2/H2O was employed as solvent.
Rights: aberto
Identifier DOI: 
Date Issue: 2001
Appears in Collections:Unicamp - Artigos e Outros Documentos

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