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Type: Artigo de periódico
Title: Factors Responsible For The Activity Of Alumina Surfaces In The Catalytic Epoxidation Of Cis-cyclooctene With Aqueous H 2o 2
Author: Rinaldi R.
Schuchardt U.
Abstract: The structural, textural, and chemical properties as well as the hydrophilicity of four different sol-gel aluminas were determined by different methods and compared with their activity in the catalytic epoxidation of cis-cyclooctene with aqueous H 2O 2. It was found that the hydrophilicity of the γ-alumina surface is the principal factor responsible for the difference in catalytic activity. The hydrophilicity of γ-alumina should be sufficient to guarantee a fast reaction with hydrogen peroxide on the surface but should not to be too high in order to allow the approach of olefin to the active sites. © 2004 Elsevier Inc. All rights reserved.
Rights: fechado
Identifier DOI: 10.1016/j.jcat.2004.06.028
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

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