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Type: Artigo de periódico
Title: Thermochemical Parameters Of Dimethyl And Di-iso-propyl Dithiocarbamate Complexes Of Palladium(ii)
Author: Botelho J.R.
Gondim A.D.
Santos I.M.G.
Dunstan P.O.
Souza A.G.
Fernandes Jr. V.J.
Araujo A.S.
Abstract: The standard molar enthalpy of formation of crystalline dialkyldithiocarbamate chelates, [Pd(S2CNR2)2], with R=CH3 and i-C3H7, was determined through reaction-solution calorimetry in 1,2-dichloroethane, at 298 K. Using the standard molar enthalpies of formation of the gaseous chelates, the homolytic (526±18 and 666±10) and heterolytic (2693±18 and 2957±10 kJ mol-1) mean enthalpies of palladium-sulphur bond dissociation were calculated.
Rights: fechado
Identifier DOI: 10.1023/B:JTAN.0000027152.50431.39
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

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