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Type: Artigo de periódico
Title: Gas-phase Polar Cycloadditions
Author: Eberlin M.N.
Abstract: The dilute gas-phase environment of mass spectrometers provides versatile and convenient medium in which chemists can form a great variety of ionic species and study their intrinsic reactivity exploring reaction mechanisms and screening for new reactions and their applications. Recent and illustrative examples of gas-phase polar cycloadditions of even and odd-electrons ions, which have been observed (some for the first time) in the solvent- and counter ion-free environment of mass spectrometers, are presented. Synthetic and analytical applications of such reactions and correlations with analogous reactions observed in solution are also discussed. © 2004 Elsevier B.V. All rights reserved.
Rights: fechado
Identifier DOI: 10.1016/j.ijms.2004.05.002
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

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