Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/94410
Type: Artigo de periódico
Title: Is Water Really Deleterious For Organometallics Anchoring Into Zeolites?
Author: De Oliveira E.C.
Pastore H.O.
Abstract: Anchoring of [(η5-C5H5) Rh(η4-C8H12)] into cavities of Na 56Y and H56Y zeolites was studied. In contrast to expectation, the zeolite degree of hydration is not a key factor in the organometallic structural integrity. The thermal behavior of the occlusion reaction is the same when the zeolites are completely or partially dehydrated, showing that total absence of water is not a necessary condition to prepare an organometallic/zeolite system. For the zeolite Na56Y the product is the organometallic fragment [(n5-C5H5)Rh] which anchors to the oxygen atoms of the framework, while for the H56Y zeolite the product is a cationic organometallic species.
Editor: 
Rights: fechado
Identifier DOI: 10.1163/1568567042420767
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-10944234891&partnerID=40&md5=a580eee8fc8e65974f41493a4845c617
Date Issue: 2004
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File Description SizeFormat 
2-s2.0-10944234891.pdf222.34 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.