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Type: Artigo de periódico
Title: Development Of A Sensor Based On Tetracyanoethylenide (litcne)/poly-l- Lysine (pll) For Dopamine Determination
Author: Luz R.D.C.S.
Damos F.S.
De Oliveira A.B.
Beck J.
Kubota L.T.
Abstract: The catalytic oxidation of dopamine (DA) at a LiTCNE (lithium tetracyanoethylenide) film modified electrode is studied by electrochemical approaches. The immobilization of LiTCNE was performed by a polymer (poly-l-lysine) to prepare this modified electrode and its application for dopamine (DA) determination is described in detail. The modified electrode showed a high activity for the electrooxidation of dopamine (DA) at E p = 0.20 V versus SCE. The modified electrode presented a wide linear response range for DA from 0.01 up to 10 μmol l-1 by differential pulse voltammetry (DPV) with a detection limit of 0.5 nmol l-1. The repeatability of the proposed sensor evaluated in term of relative standard deviation was 3.2% for n = 10. The sensor was applied for the determination of dopamine in pharmaceutical formulations and the average recovery for these samples was 101.9 (±0.1)%. © 2004 Elsevier Ltd. All rights reserved.
Rights: fechado
Identifier DOI: 10.1016/j.electacta.2004.11.012
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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