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Type: Artigo de periódico
Title: Highly Regio- And Stereoselective Heck Reaction Of Allylic Esters With Arenediazonium Salts: Application To The Synthesis Of Kavalactones
Author: Moro A.V.
Cardoso F.S.P.
Correia C.R.D.
Abstract: Image Presented A highly efficient palladium-catalyzed Heck reaction of allylic esters with arenediazonium salts is described. The reaction proceeds under mild conditions, with excellent to total regio- and stereochemical control and with retention of the traditional leaving group. Furthermore, the generality of the present methodology is illustrated by the short total synthesis of the natural kavalactones, yangonine, (±)-methysticin, and (±)-dihydromethysticin. © 2009 American Chemical Society.
Rights: fechado
Identifier DOI: 10.1021/ol901416e
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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