Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/93007
Type: Artigo de periódico
Title: Highly Regio- And Stereoselective Heck Reaction Of Allylic Esters With Arenediazonium Salts: Application To The Synthesis Of Kavalactones
Author: Moro A.V.
Cardoso F.S.P.
Correia C.R.D.
Abstract: Image Presented A highly efficient palladium-catalyzed Heck reaction of allylic esters with arenediazonium salts is described. The reaction proceeds under mild conditions, with excellent to total regio- and stereochemical control and with retention of the traditional leaving group. Furthermore, the generality of the present methodology is illustrated by the short total synthesis of the natural kavalactones, yangonine, (±)-methysticin, and (±)-dihydromethysticin. © 2009 American Chemical Society.
Editor: 
Rights: fechado
Identifier DOI: 10.1021/ol901416e
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-68949132409&partnerID=40&md5=372a6869f62d53d11eee3847ceba603a
Date Issue: 2009
Appears in Collections:Unicamp - Artigos e Outros Documentos

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