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Type: Artigo de evento
Title: Raman And Infrared Spectroscopy Of Sr2b′uo6 (b′ = Ni; Co) Double Perovskites
Author: Moreira A.F.L.
Garcia-Flores A.F.
Granado E.
Massa N.E.
Pinacca R.M.
Pedregosa J.C.
Carbonio R.E.
Munoz A.
Martinez-Lope M.J.
Alonso J.A.
Del Campo L.
Meneses D.D.S.
Echegut P.
Abstract: Temperature dependent normal modes and lattice thermal expansion of Sr 2B′UO6 (B′ = Ni, Co) double perovskites were investigated by Raman/infrared spectroscopies and synchrotron X-ray diffraction, respectively. Monoclinic crystal structures with space group P21/n were confirmed for both compounds, with no clear structural phase transition between 10 and 400 K. As predicted for this structure, the first-order Raman and infrared spectra show a plethora of active modes. In addition, the Raman spectra reveal an enhancement of the integrated area of an oxygen stretching mode, which is also observed in higher-order Raman modes, and an anomalous softening of ∼1 cm-1 upon cooling below T* ∼ 300 K. In contrast, the infrared spectra show conventional temperature dependence. The band profile phonon anomalies are possibly related to an unspecified electronic property of Sr2B′UO6 (B′ = Ni, Co). © 2010 Elsevier B.V. All rights reserved.
Rights: fechado
Identifier DOI: 10.1016/j.vibspec.2010.08.008
Date Issue: 2010
Appears in Collections:Unicamp - Artigos e Outros Documentos

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