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Type: Artigo de periódico
Title: Efficiency Of Zeolite Mcm-22 With Different Sio2/al 2o3 Molar Ratios In Gas Phase Glycerol Dehydration To Acrolein
Author: Carrico C.S.
Cruz F.T.
Santos M.B.
Pastore H.O.
Andrade H.M.C.
Mascarenhas A.J.S.
Abstract: The gas-phase dehydration of glycerol was conducted over MCM-22 zeolite with different SiO2/Al2O3 molar ratios. MCM-22 zeolites were synthesized and characterized by XRD, FTIR, TG, SEM, EDX, textural analysis by N2 physisorption and NH3-TPD. The MCM-22 zeolites have presented good crystallinity, high surface areas and a decreased amount of acid sites and strength with increasing SiO2/Al 2O3 ratio was observed. The glycerol conversion and acrolein selectivity increased with increasing reaction temperature from 280 C to 320 C on MCM-22 (30) catalyst. As long as the concentration of glycerol solution was in the range from 10% to 36.6%, there was no noticeable difference in the glycerol conversion but the acrolein yield increased with water amount in the feed. The glycerol conversion and selectivity to acrolein at 320 C using glycerol feed of 36.6% during 10 h of reaction decreased in the following order: MCM-22 (30) > MCM-22 (50) > MCM-22 (80). This result shows that glycerol dehydration to acrolein is strongly dependent on the acid sites density and external surface area of the zeolite MCM-22. © 2013 Elsevier Inc. All rights reserved.
Rights: fechado
Identifier DOI: 10.1016/j.micromeso.2013.07.020
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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