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Type: Artigo de periódico
Title: Use Of The Optical Lithography In The Development Of Disposable Carbon Based Electrodes [uso Da Litografia óptica No Desenvolvimento De Eletrodos Descartáveis à Base De Carbono]
Author: Mello L.D.
Kisner A.
Pereira A.
Kubota L.T.
Abstract: In this study, carbon-based electrodes for disposable use were constructed using the technique of optical lithography. The process consisted in the irradiation of UV light on a layer of photosensitive resin (SU-8 50) deposited on a substrate of PVC. The pattern obtained electrode was filled with carbon paste. The electrodes were characterized by cyclic voltammetric using the reversible system Fe(CN)6 3-/Fe(CN)6 4- in KCl 0.1 mol L-1 and electrochemical impedance spectroscopy (EIS). The electrodes showed an E°' = 1/2 (Epa + Epc) ≈ 229 (± 2) mV vs SCE (n = 4), with ΔEp ≈ 235 (± 14) mV (n = 4). Other studies showed a linear behavior of the peak current (Ip) both anode and cathode with v1/2, probably due to diffuse contribution and/or electron transfer kinetics of the reaction. These parameters are in accordance to with those obtained for screen-printed electrode described in the literature. The good results obtained show the suitability of the electrodes for analytical applications such as development of sensors.
Rights: aberto
Identifier DOI: 10.4025/actascitechnol.v35i1.11915
Date Issue: 2013
Appears in Collections:Unicamp - Artigos e Outros Documentos

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