Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/86480
Type: Artigo de periódico
Title: Crystal Structure Of (3e)-3-(2,4-dinitrophenoxymethyl)-4-phenylbut-3-en-2-one
Author: Caracelli I.
Maganhi S.H.
Moran P.J.S.
Paula B.R.S.D.
Delling F.N.
Tiekink E.R.T.
Abstract: In the title compound, C17H14N2O6, the conformation about the C=C double bond [1.345(2)Å] is E, with the ketone moiety almost coplanar [C-C-C-C torsion angle = 9.5(2)°] along with the phenyl ring [C-C-C-C = 5.9(2)°]. The aromatic rings are almost perpendicular to each other [dihedral angle = 86.66(7)°]. The 4-nitro moiety is approximately coplanar with the benzene ring to which it is attached [O-N-C-C = 4.2(2)°], whereas the one in the ortho position is twisted [O-N-C-C = 138.28(13)°]. The molecules associate via C-H⋯O interactions, involving both O atoms from the 2-nitro group, to form a helical supramolecular chain along [010]. Nitro-nitro N⋯O interactions [2.8461(19)Å] connect the chains into layers that stack along [001].
Editor: International Union of Crystallography
Rights: aberto
Identifier DOI: 10.1107/S1600536814018819
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-84907014906&partnerID=40&md5=e975a253ec6ba1389b834960a6883f0d
Date Issue: 2014
Appears in Collections:Unicamp - Artigos e Outros Documentos

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