Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/85439
Type: Artigo de periódico
Title: Surface Effects On The Mechanical Elongation Of Aucu Nanowires: De-alloying And The Formation Of Mixed Suspended Atomic Chains
Author: Lagos M.J.
Autreto P.A.S.
Bettini J.
Sato F.
Dantas S.O.
Galvao D.S.
Ugarte D.
Abstract: We report here an atomistic study of the mechanical deformation of AuxCu(1- x ) atomic-size wires (nanowires (NWs)) by means of high resolution transmission electron microscopy experiments. Molecular dynamics simulations were also carried out in order to obtain deeper insights on the dynamical properties of stretched NWs. The mechanical properties are significantly dependent on the chemical composition that evolves in time at the junction; some structures exhibit a remarkable de-alloying behavior. Also, our results represent the first experimental realization of mixed linear atomic chains (LACs) among transition and noble metals; in particular, surface energies induce chemical gradients on NW surfaces that can be exploited to control the relative LAC compositions (different number of gold and copper atoms). The implications of these results for nanocatalysis and spin transport of one-atom-thick metal wires are addressed.
Editor: American Institute of Physics Inc.
Rights: aberto
Identifier DOI: 10.1063/1.4913625
Address: http://www.scopus.com/inward/record.url?eid=2-s2.0-84924160021&partnerID=40&md5=7da643c3d245b674a2b54f001c02f81e
Date Issue: 2015
Appears in Collections:Unicamp - Artigos e Outros Documentos

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