Please use this identifier to cite or link to this item:
Type: Artigo de periódico
Title: NiO Nanoparticles Dispersed in Mesoporous Silica Glass
Author: Carneiro, NM
Nunes, WC
Borges, RP
Godinho, M
Fernandez-Outon, LE
Macedo, WAA
Mazali, IO
Abstract: We have studied the magnetic properties of NiO nanoparticles dispersed into mesoporous silica glass with three particle size distributions obtained using the bottom-up nanofabrication technique. The samples were characterized by XRD, Raman, and TEM and found to consist of monodispersed rock salt structure NiO nanoparticles. The magnetic results indicate that the particles can be considered as an antiferromagnetically ordered core with an uncompensated magnetic moment, and a magnetically disordered surface. The magnetization loops exhibit a loop shift with intriguing temperature dependence. Furthermore, an increase in the average blocking temperature is observed with increases in the number of impregnation-decomposition cycles. These results are discussed considering the influence of the magnetic interaction on the core-shell structure of the nanoparticles.
Country: EUA
Editor: Amer Chemical Soc
Rights: fechado
Identifier DOI: 10.1021/jp1046886
Date Issue: 2010
Appears in Collections:Unicamp - Artigos e Outros Documentos

Files in This Item:
File Description SizeFormat 
WOS000283703500003.pdf1.47 MBAdobe PDFView/Open

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.