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Type: Artigo de periódico
Title: Oxidations with acyl nitrates: A simple and rapid method for preparing quinones, ketones and aldehydes
Author: deOliveira, AP
Moreira, BG
Moran, PJS
Rodrigues, JAR
Abstract: Hydroquinones are oxidized rapidly and quantitatively with acyl nitrates or trimethylsilyl nitrates to quinones. Primary and secondary alcohols are oxidized to aldehydes and ketones in good yields with acyl nitrates suported on montmorillonite or chrysotile. A mechaninsm is proposed based on a nitrate intermediate isolated from the reaction mixture. Copyright (C) 1996 Elsevier Science Ltd
Country: Inglaterra
Editor: Pergamon-elsevier Science Ltd
Rights: fechado
Identifier DOI: 10.1016/0040-4039(96)01008-8
Date Issue: 1996
Appears in Collections:Unicamp - Artigos e Outros Documentos

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