Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/81570
Type: Artigo de periódico
Title: Oxidation with the 'O-2-H2O2-vanadium complex pyrazine-2-carboxylic acid' reagent - 9. Oxidation of cyclohexene and decalin
Author: Schuchardt, U
Guerreiro, MC
Shul'pin, GB
Abstract: The oxidation of cyclohexene with hydrogen peroxide catalyzed by a vanadium complex and pyrazine-2-carboxylic acid (PCA) in air results in the formation of cyclohex-2-enyl hydroperoxide as the main product and cyclohex-2-enol, cyclohex-2-enone, cyclohex-3-enyl hydroperoxide, cyclohex-3-enol, cyclohexanol, cyclohexane, and 1,2-epoxycyclohexane in lesser amounts. The composition of the products of oxidation of decalin isomers with the system in question is similar to those obtained in the photochemical oxidation with hydrogen peroxide in air and in the oxidation with air in the presence of anthraquinone. A proposed mechanism for the oxidation includes the initiation by hydroxyl radicals generated from hydrogen peroxide under the action of the V-PCA system.
Subject: activation of C-H bond
alkanes
hydroxyl radicals
decalin
metallocomplex catalysis
oxidation
hydrogen peroxide
vanadium complexes
cyclohexene
Country: EUA
Editor: Plenum Publ Corp
Rights: fechado
Identifier DOI: 10.1007/BF02498943
Date Issue: 1998
Appears in Collections:Unicamp - Artigos e Outros Documentos

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