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Type: Artigo de periódico
Title: Oxidation with the 'O-2-H2O2-vanadium complex pyrazine-2-carboxylic acid' reagent - 9. Oxidation of cyclohexene and decalin
Author: Schuchardt, U
Guerreiro, MC
Shul'pin, GB
Abstract: The oxidation of cyclohexene with hydrogen peroxide catalyzed by a vanadium complex and pyrazine-2-carboxylic acid (PCA) in air results in the formation of cyclohex-2-enyl hydroperoxide as the main product and cyclohex-2-enol, cyclohex-2-enone, cyclohex-3-enyl hydroperoxide, cyclohex-3-enol, cyclohexanol, cyclohexane, and 1,2-epoxycyclohexane in lesser amounts. The composition of the products of oxidation of decalin isomers with the system in question is similar to those obtained in the photochemical oxidation with hydrogen peroxide in air and in the oxidation with air in the presence of anthraquinone. A proposed mechanism for the oxidation includes the initiation by hydroxyl radicals generated from hydrogen peroxide under the action of the V-PCA system.
Subject: activation of C-H bond
hydroxyl radicals
metallocomplex catalysis
hydrogen peroxide
vanadium complexes
Country: EUA
Editor: Plenum Publ Corp
Citation: Russian Chemical Bulletin. Plenum Publ Corp, v. 47, n. 2, n. 247, n. 252, 1998.
Rights: fechado
Identifier DOI: 10.1007/BF02498943
Date Issue: 1998
Appears in Collections:Unicamp - Artigos e Outros Documentos

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