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Type: Artigo de periódico
Title: Liquid-liquid equilibrium data and thermodynamic modeling, at T/K=298.2, in the washing step of ethyl biodiesel production from crambe, fodder radish and macauba pulp oils
Author: Basso, RC
Miyake, FH
Meirelles, AJD
Batista, EAC
Abstract: In this work, pseudo-ternary liquid-liquid equilibrium data were obtained for three systems composed for water + ethanol + ethyl biodiesel from crambe, fodder radish and macauba pulp oils, at T/K = 298.2. Ethanol, which distributes in both phases, had greater affinity for the water-rich phase. Biodiesels and water showed almost complete immiscibility. Modeling with the NRTL and UNIQUAC thermodynamic models was performed, resulting in average deviations ranging from 0.49% to 1.29%. UNIFAC-LLE and UNIFAC-Dortmund were used in prediction of the liquid-liquid equilibrium of these systems, resulting in average deviations ranging from 1.91% to 2.27% for the systems containing biodiesel from crambe and fodder radish oils, and ranging from 3.17% to 3.28% for biodiesel from macauba oil. (C) 2013 Elsevier Ltd. All rights reserved.
Subject: Biodiesel
Liquid-liquid equilibrium
Thermodynamic model
Water washing
Pseudo-ternary systems
Country: Inglaterra
Editor: Elsevier Sci Ltd
Rights: fechado
Identifier DOI: 10.1016/j.fuel.2013.09.020
Date Issue: 2014
Appears in Collections:Unicamp - Artigos e Outros Documentos

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