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Type: Artigo de periódico
Title: Pre-concentration of rare earths using silica gel loaded with 1-(2-pyridylazo)-2-naphthol (PAN) and determination by energy dispersive X-ray fluorescence
Author: Cornejo-Ponce, L
Peralta-Zamora, P
Bueno, MIMS
Abstract: The determination of a single rare earth element in a mixture with other species of this family is a very challenging problem in analytical chemistry due to the close similarity of their chemical properties. In this work, a liquid-solid extraction procedure for praseodymium, neodymium, samarium and yttrium mixtures and subsequent determination by energy dispersive X-ray fluorescence spectrometry is described. The pre-concentration procedure, which involves the use of silica modified with 1-(2-pyridyrazo)-2-naphthol, permits complete recovery of the ran earths and significant sensitivity enhancement in comparison with direct determination in the aqueous phase. Determinations in quaternary mixtures show typical precisions and accuracies of 3% and 5%, respectively. (C) 1998 Elsevier Science B.V. All rights reserved.
Subject: pre-concentration
rare earths
X-ray fluorescence
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/S0039-9140(98)00002-2
Date Issue: 1998
Appears in Collections:Unicamp - Artigos e Outros Documentos

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