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Type: Artigo de periódico
Title: Ligand interchange from bis(3,3-pentamethylenediaziridine)cobalt dichloride. Evidence of metallacyclic heterobimetallic intermediate formation
Author: dosSantos, PF
Abstract: Ligand interchange can be observed in reactions of bis(3,3-pentamethylenediaziridine)cobalt dichloride with Pd(II), Cd(II), Ni(II) and Rh(III) chlorides. In the case of the reaction with bis(benzonitrile)palladium dichloride the stereochemistry of the product isolated indicates that the intermediate involved in this reaction is a metallacyclic heterobimetallic complex which, depending on the combination of the metals, can be isolated.
Subject: ligand interchange
Country: Brasil
Editor: Soc Brasileira Quimica
Rights: aberto
Date Issue: 1996
Appears in Collections:Unicamp - Artigos e Outros Documentos

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