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|Type:||Artigo de periódico|
|Title:||Density, refraction index and vapor-liquid equilibria of N-methyl-2-hydroxyethylammonium butyrate plus (methyl acetate or ethyl acetate or propyl acetate) at several temperatures|
|Abstract:||This paper reports the densities, refraction indices, and vapor liquid equilibria for binary systems ester + N-methyl-2-hydroxyethylammonium butyrate (m-2-HEAB): methyl acetate (1) + m-2-HEAB (2), ethyl acetate (1) + m-2-HEAB and propyl acetate (1) + m-2-HEAB (2). The excess molar volumes, deviations in the refraction index, apparent molar volumes, and thermal expansion coefficients for the binary systems were fitted to polynomial equations. The Peng-Robinson equation of state, coupled with the Wong-Sandler mixing rule, is used to describe the experimental data. Since the predictive activity coefficient model COSMO-SAC is used in the Wong-Sandler mixing rule, the resulting thermodynamic model is a completely predictive one. The prediction results for the density and for the vapor-liquid equilibria have a deviation lower than 1.0% and 1.1%, respectively. (c) 2013 Elsevier Ltd. All rights reserved.|
|Editor:||Academic Press Ltd- Elsevier Science Ltd|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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