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Type: Artigo de periódico
Title: Synthesis, characterization and thermal behavior of 18 cadmium halides adducts involving ethyleneurea, ethylenethiourea and propyleneurea
Author: de Farias, RF
Martinez, L
Airoldi, C
Abstract: In this work we report on the synthesis, characterization and thermal behavior of 18 adducts of general formula CdX2.nL (where X = Cl, Br and I, n = 1 and 2, and L = ethyleneurea (eu), ethylenethiourea (etu) and propyleneurea (pu)). The IR spectroscopy results shows that for the eu and pu adducts, coordination occurs through oxygen, whereas for etu, nitrogen is used as coordination site. The thermogravimetric curves shows that the synthesized adducts releases the ligand molecules in a single mass loss step, In considering adducts with same stoichiometry, the observed thermal stability trend is etu > pu > eu. (C) 2001 Elsevier Science B.V. All rights reserved.
Subject: cyclic amides
cadmium halides
Country: Holanda
Editor: Elsevier Science Bv
Citation: Thermochimica Acta. Elsevier Science Bv, v. 376, n. 1, n. 91, n. 94, 2001.
Rights: fechado
Identifier DOI: 10.1016/S0040-6031(01)00559-7
Date Issue: 2001
Appears in Collections:Unicamp - Artigos e Outros Documentos

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