Please use this identifier to cite or link to this item:
|Type:||Artigo de periódico|
|Title:||Synthesis of the C4-C17 Fragment of Saliniketals A and B|
|Abstract:||A highly stereoselective synthesis of the C4C17 fragment of saliniketals A and B was completed. The key steps in this synthesis included a syn-aldol reaction mediated by a boron enolate and a double diastereodifferentiating aldol reaction mediated by a titanium enolate. Moreover, a substrate-controlled Grignard reaction, an intramolecular Wacker-type cyclization and a SeyferthGilbert homologation provided the C4C17 fragment of saliniketals A and B in 16 steps and with a 7% overall yield.|
|Editor:||Wiley-v C H Verlag Gmbh|
|Citation:||European Journal Of Organic Chemistry. Wiley-v C H Verlag Gmbh, n. 14, n. 2930, n. 2939, 2013.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.