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|Type:||Artigo de periódico|
|Title:||Synthesis of the C4-C17 Fragment of Saliniketals A and B|
|Abstract:||A highly stereoselective synthesis of the C4C17 fragment of saliniketals A and B was completed. The key steps in this synthesis included a syn-aldol reaction mediated by a boron enolate and a double diastereodifferentiating aldol reaction mediated by a titanium enolate. Moreover, a substrate-controlled Grignard reaction, an intramolecular Wacker-type cyclization and a SeyferthGilbert homologation provided the C4C17 fragment of saliniketals A and B in 16 steps and with a 7% overall yield.|
|Editor:||Wiley-v C H Verlag Gmbh|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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