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|Type:||Artigo de periódico|
|Title:||Dba-free palladium intermediates of the Heck-Matsuda reaction|
|Abstract:||The 'dba-free' Heck-Matsuda reaction was investigated via direct ESI-MS(/MS) monitoring. Palladium species involved in the reduction of Pd(II) during a Wacker type reaction and several 'dba-free' arylpalladium transient complexes were detected and characterized. Based on these findings, a more comprehensible catalytic cycle for this pivotal reaction is suggested.|
|Editor:||Royal Soc Chemistry|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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