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Type: Artigo de periódico
Title: Towards the total synthesis of stawamycin. Synthesis of C11-C21 fragment.
Author: Dias, LC
Jardim, LSA
Ferreira, AA
Soarez, HU
Abstract: The carbocyclic (C11-C21) fragment of Stawamycin has been prepared by a sequence involving 11 steps (10% overall yield) from methyl (R)-(-)-3-hydroxy-2-methylpropionate. Key steps are Pd-catalyzed Stille coupling reaction between a vinyl iodide and a vinylstannane followed by an intramolecular Diels-Alder cycloaddition reaction to afford the desired adduct as the major isomer together with three other possible adducts in 78% overall yield.
Subject: intramolecular Diels-Alder reaction
Stille coupling
herpes virus inhibitor
Country: Brasil
Editor: Soc Brasileira Quimica
Rights: aberto
Identifier DOI: 10.1590/S0103-50532001000400003
Date Issue: 2001
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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