Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/77408
Type: Artigo de periódico
Title: Anchored fibrous chrysotile silica and its ability in using nitrogen basic centers on cation complexing from aqueous solution
Author: da Fonseca, MG
da Silva, EC
Machado, RSD
Arakaki, LNH
Espinola, JGP
Oliveira, SF
Airoldi, C
Abstract: Amorphous silica gel obtained through natural chrysotile was lixiviated with hydrochloric acid, which was chemically modified with organosilanes (H3CO)(3)SiR, where R corresponds to the organic moieties -CH2CH2CH2NH2 and -CH2CH2CH2NHCH2CH2NH2, yielding solids named SIL1 and SIL2. These anchored silicas showed 2.14 +/- 0.05 and 1.90 +/- 0.04 mmol g(-1) of attached amino groups on surfaces SIL1 and SIL2, respectively. The isotherms of adsorption data were obtained by batchwise process, whose values were adjusted to a modified Langmuir equation. The maximum adsorption capacity showed the sequence for copper and cobalt as 1.02, 0.35 mmol g(-1) on SIL2 and 0.71, 0.26 mmol g(-1) on SIL1, respectively. By using calorimetric titration, the enthalpy change of the adsorption process was 18.77 +/- 0.75 and -43.29 +/- 1.08 kJ mol(-1) for copper, 12.70 +/- 0.57 and -169.3 +/- 1.23 kJ mol(-1) for cobalt on SIL1 and SIL2, respectively. Negative Gibbs free energy values are in agreement with the spontaneity of the proposed reactions involving both divalent cations, when complexed by basic amino groups attached to pendant chain covalently bonded to the inorganic surface. (C) 2003 Elsevier B.V. All rights reserved.
Subject: chrysotile
adsorption
calorimetry
copper
cobalt
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/S0927-7757(03)00421-7
Date Issue: 2003
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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