Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/76863
Type: Artigo de periódico
Title: Adsorption of arsenic(III) into modified lamellar Na-magadiite in aqueous medium-Thermodynamic of adsorption process
Author: Guerra, DL
Pinto, AA
Airoldi, C
Viana, RR
Abstract: Synthetic Na-magadiite sample was used for organofunctionalization process with N-propyldiethylene-trimethoxysilane and bis[3-(triethoxysilyl)propyl]tetrasulfide, after expanding the interlayer distance with polar organic solvents Such as dimethylsulfoxide (DMSO). The resulted materials were submitted to process of adsorption with arsenic solution at pH 2.0 and 298 +/- 1K. The adsorption isotherms were adjusted using a modified Langmuir equation with regression nonlinear: the net thermal effects obtained from calorimetric titration measurements were adjusted to a modified Langmuir equation. The adsorption process was exothermic (Delta(int)H = -4.15-5.98 kJ mol(-1)) accompanied by increase in entropy (Delta(int)S = 41.32-62.20Jk(-1) mol(-1)) and Gibbs energy (Delta(int)G = -22.44-24.56 kJ mol(-1)). The favorable values corroborate with the arsenic (III)/basic reactive centers interaction at the solid-liquid interface in the spontaneous process. (C) 2008 Published by Elsevier Inc.
Subject: Chemical properties
Nanocomposites
Surfaces
Interfaces
Country: EUA
Editor: Academic Press Inc Elsevier Science
Rights: fechado
Identifier DOI: 10.1016/j.jssc.2008.09.006
Date Issue: 2008
Appears in Collections:Unicamp - Artigos e Outros Documentos

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