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|Type:||Artigo de periódico|
|Title:||Adsorption of arsenic(III) into modified lamellar Na-magadiite in aqueous medium-Thermodynamic of adsorption process|
|Abstract:||Synthetic Na-magadiite sample was used for organofunctionalization process with N-propyldiethylene-trimethoxysilane and bis[3-(triethoxysilyl)propyl]tetrasulfide, after expanding the interlayer distance with polar organic solvents Such as dimethylsulfoxide (DMSO). The resulted materials were submitted to process of adsorption with arsenic solution at pH 2.0 and 298 +/- 1K. The adsorption isotherms were adjusted using a modified Langmuir equation with regression nonlinear: the net thermal effects obtained from calorimetric titration measurements were adjusted to a modified Langmuir equation. The adsorption process was exothermic (Delta(int)H = -4.15-5.98 kJ mol(-1)) accompanied by increase in entropy (Delta(int)S = 41.32-62.20Jk(-1) mol(-1)) and Gibbs energy (Delta(int)G = -22.44-24.56 kJ mol(-1)). The favorable values corroborate with the arsenic (III)/basic reactive centers interaction at the solid-liquid interface in the spontaneous process. (C) 2008 Published by Elsevier Inc.|
|Editor:||Academic Press Inc Elsevier Science|
|Citation:||Journal Of Solid State Chemistry. Academic Press Inc Elsevier Science, v. 181, n. 12, n. 3374, n. 3379, 2008.|
|Appears in Collections:||Unicamp - Artigos e Outros Documentos|
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