Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/76845
Type: Artigo de periódico
Title: Adsorption and thermodynamic studies of Cu(II) and Zn(II) on organofunctionalized-kaolinite
Author: Guerra, DL
Airoldi, C
de Sousa, KS
Abstract: Kaolinite-bearing clay samples from Perus, Sao Paulo state, Brazil, were used for chemical modification process with dimethyl sulfoxide and organofunctionalized with the silyating agent (RO)(3)Si(CH(2))(3)NH(CH(2))(2)NH(2) in the present study. The resulting material and natural kaolinite were subjected adsorpion process with Cu(II) and Zn(II) from aqueous solution at pH 6.0 and controlated temperature of 298 K. The Langmuir adsorption isotherm model has been applied to fit the experimental data. The results showed that the chemical modification process increases the basal spacing of the natural kaolinite from 0.711 to 0.955 nm. The energetic effects caused by Cu(II) and Zn(II) interactions were determined through calorimetric titration at the solid-liquid interface and gave a net thermal effect that enabled the calculation of the exothermic values and the equilibrium constant. (C) 2008 Published by Elsevier B.V.
Subject: kaolinite
adsorption isotherms
calorimetry
thermodynamic
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.apsusc.2008.02.017
Date Issue: 2008
Appears in Collections:Unicamp - Artigos e Outros Documentos

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