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Type: Artigo de periódico
Title: Addition of silylated carbon nucleophiles to iminium and cyclic N-acyliminium ions promoted by InCl3
Author: Russowsky, D
Petersen, RZ
Godoi, MN
Pilli, RA
Abstract: InCl3 was used as Lewis acid in the addition of silyl enolates and allyltrimethylsilane to aromatic aldimines and cyclic N-acyliminium ions derived from 5-acetoxylactams affording beta -aminocarbonyl systems and allyl adducts, respectively, in reasonable to good yields. The diastereofacial selectivity of cyclic N-acyliminium ions was investigated. (C) 2000 Elsevier Science Ltd. All rights reserved.
Country: Inglaterra
Editor: Pergamon-elsevier Science Ltd
Rights: fechado
Identifier DOI: 10.1016/S0040-4039(00)01828-1
Date Issue: 2000
Appears in Collections:Unicamp - Artigos e Outros Documentos

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