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Type: Artigo de periódico
Title: Addition of allyltrichlorostannanes to aldehydes: application in the synthesis of 4-N-Boc-amino-3-hydroxy ketones
Author: Dias, LC
Fattori, J
Perez, CC
Abstract: We wish to describe here the diastereoselective reaction between chiral N-Boc-alpha-amino aldehydes and achiral allyltrichlorostannanes leading to 1,2-syn-N-Boc-alpha-amino alcohols, which are treated with catalytic amounts of OSO4 in the presence of NaIO4 to provide the corresponding 4-N-Boc-amino-3-hydroxy ketones. (C) 2007 Elsevier Ltd. All rights reserved.
Subject: allyltrichlorostannane
Country: Inglaterra
Editor: Pergamon-elsevier Science Ltd
Rights: fechado
Identifier DOI: 10.1016/j.tetlet.2007.11.072
Date Issue: 2008
Appears in Collections:Unicamp - Artigos e Outros Documentos

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