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Type: Artigo de periódico
Title: Addition of activated olefins to cyclic N-acyliminium ions in ionic liquids
Author: Pilli, RA
Robello, LG
Camilo, NS
Dupont, J
Lapis, AAM
Neto, BAD
Abstract: Organoindate(III) ionic liquid ((BMIInCl4)-In-.) was successfully employed in the nucleophilic addition of allyltrimethylsilane, silyl enol ethers and ketene silyl acetals to in situ generated cyclic N-acyliminium ions at room temperature without the need of an external Lewis acid. The corresponding alpha-substituted heterocycles were obtained in good yields and the recovered ionic liquid phase could be reused at least three times. (c) 2006 Elsevier Ltd. All rights reserved.
Country: Inglaterra
Editor: Pergamon-elsevier Science Ltd
Rights: fechado
Identifier DOI: 10.1016/j.tetlet.2005.12.102
Date Issue: 2006
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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