Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/76319
Type: Artigo de periódico
Title: A new organofunctionalized silica containing thioglycolic acid incorporated for divalent cations removal-A thermodyamic cation/basic center interaction
Author: Silva, ALR
Sousa, KS
Germano, AFS
Oliveira, VV
Espinola, JGR
Fonseca, MG
Airoldi, C
Arakaki, T
Arakaki, LNH
Abstract: The silylating agent 3-[2-(2-aminoethylamino)ethylamino]propyl-trimethoxysilane was previously immobilized onto silica gel in heterogeneous route, followed by incorporation of thioglycolic acid. The elemental analysis for this final organofunctionalized silica has a degree of pendant chain of 0.27 mmol per gram of the inorganic support. Infrared spectroscopy, thermogravimetry and (13)CNMR data are in agreement with the covalent bond of organic moieties on silica, with increase in basic centers attached to these pendant chains, which adsorb divalent copper, nickel and cobalt cations from aqueous solution. The data from batch adsorption process were adjusted to a modified Langmuir equation, to give the maximum retention capacity Cu(II)>Ni(II)>Co(II). This same cation/basic centers interaction was calorimetrically followed through titration technique. The enthalpies of these processes are: -3.03 +/- 0.01, -3.73 +/- 0.02, and -2.75 +/- 0.01 kJ mol(-1) for Cu(II), Ni(II), and Co(II), respectively. The standard molar Gibbs free energies are in agreement with the spontaneity of the proposed reactions between cation and basic center. (C) 2008 Elsevier B.V. All rights reserved.
Subject: Silica immobilization
Thioglycolic acid
Calorimetric titration
Thermodynamic data
Cation removal
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.colsurfa.2008.09.010
Date Issue: 2009
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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