Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/76077
Type: Artigo de periódico
Title: A model for selective adsorption with a localized adsorption energy
Author: Mafra, MR
Cardozo-Filho, L
Voll, FAP
Evangelista, LR
Guirardello, R
Barbero, G
Abstract: A model for the selective adsorption phenomenon in an isotropic liquid considering a localized adsorption energy is proposed. The fundamental equations governing the adsorption phenomena are established, by considering the mass balance equation in a limited region close to the interface. The electric field distribution inside the sample and the behavior of the chemical potential are determined as a function of the initial concentration of the fluid phase. This model allows us to obtain isotherms that lie outside the Langmuir approximation, because the effective potentials relevant to the adsorption process are determined in a self-consistent manner. (C) 2010 Elsevier B.V. All rights reserved.
Subject: Adsorption
Poisson-Boltzmann
Adsorption model
Country: Holanda
Editor: Elsevier Science Bv
Rights: fechado
Identifier DOI: 10.1016/j.colsurfa.2010.01.048
Date Issue: 2010
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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