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Type: Artigo de periódico
Title: Silicone sensing phase for detection of aromatic hydrocarbons in water employing near-infrared spectroscopy
Author: Albuquerque, JS
Pimentel, MF
Silva, VL
Raimundo, IM
Rohwedder, JJR
Pasquini, C
Abstract: The use of silicone for detection of aromatic hydrocarbons in water using near-infrared spectroscopy is proposed. A sensing phase of poly(dimethylsiloxane) (PDMS) was prepared, and a rod of this material was adapted to a transflectance probe for measurements from 850 to 1800 nm. Deionized water samples contaminated separately with known amounts of benzene, toluene, ethylbenzene, and m-xylene were used for evaluation of the PDMS sensing phase, and measurements were made in a closed reactor with constant stirring. Equilibrium states were obtained after 90, 180, 360, and 405 min for benzene, toluene, ethylbenzene, and m-xylene, respectively. The PDMS sensing phase showed a reversible response, presenting linear response ranges up to 360, 290, 100, and 80 mg L-1, with detection limits of 8.0, 7.0, 2.6, and 3.0 mg L-1 for benzene, toluene, ethylbenzene, and m-xylene, respectively. Reference spectra obtained with different rods showed a relative standard deviation of 0.5%, indicating repeatability in the sensing phase preparation. A relative standard deviation of 6.7% was obtained for measurements performed with six different rods, using a 52 mg L-1 toluene aqueous solution. The sensing phase was evaluated for identification of sources of contamination of water in simulated studies, employing Brazilian gasoline type A (without ethanol), gasoline type C (with 25% of anhydrous ethanol), and diesel fuel. Principal component analysis was able to classify the water in distinct groups, contaminated by gasoline A, gasoline C, or diesel fuel.
Country: EUA
Editor: Amer Chemical Soc
Rights: fechado
Identifier DOI: 10.1021/ac0495788
Date Issue: 2005
Appears in Collections:Unicamp - Artigos e Outros Documentos

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