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Type: Artigo de periódico
Title: Site and stereoselectivity of the cyclopropanation of unsymmetrically substituted 1,3-dienes by the Simmons-Smith reaction.
Author: Guerreiro, MC
Schuchardt, U
Abstract: In the Simmons-Smith reaction, 1,3-dienes are preferentially cyclopropanated at the more electron-rich double bond to afford the trans-vinylcyclopropane; an allylic hydroxyl group increases the reactivity and directs the cyclopropanation to the adjacent double bond.
Country: EUA
Editor: Taylor & Francis Inc
Rights: fechado
Identifier DOI: 10.1080/00397919608002620
Date Issue: 1996
Appears in Collections:Unicamp - Artigos e Outros Documentos

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