Please use this identifier to cite or link to this item: http://repositorio.unicamp.br/jspui/handle/REPOSIP/74199
Type: Artigo de periódico
Title: Simultaneous determination of calcium and potassium in coconut water by a flow-injection method with tubular potentiometric sensors
Author: Chumbimuni-Torres, KY
Kubota, LT
Abstract: In the present work, a simultaneous determination of calcium and potassium in coconut water samples using a flow-injection system with tubular ion-selective electrodes (ISEs) in series is described. The samples were injected into a 0.1 mol L-1 HEPES (pH = 6.0) carrier solution, using an injection volume of 100 mu L and a flow of 2.0 mL min(-1) in the FIA system. The electrodes developed exhibited nernstian response for calcium and potassium in the concentration range between 1.0 x 10(-5) and 1.0 x 10(-1) mol L-1 with detection limits of 5.6 x 10(-6) mol L-1 for calcium and 9.5 x 10(-6) mol L-1 for potassium. And no significant interference between both ions was observed. The flow-injection analysis (FIA) system with tubular ISEs was suitable for the simultaneous calcium and potassium on-line monitoring. The determination of potassium presented good results when compared to the reference method. And the recovery results were 95 +/- 1% for calcium and 102 +/- 2% for potassium, showing a good evidence of the accuracy of the method. (c) 2005 Elsevier Inc. All rights reserved.
Subject: FIA
ISE
potassium and calcium determination
Country: EUA
Editor: Academic Press Inc Elsevier Science
Rights: fechado
Identifier DOI: 10.1016/j.jfca.2005.09.006
Date Issue: 2006
Appears in Collections:Artigos e Materiais de Revistas Científicas - Unicamp

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